6-22
The proper atomic energy levels are populated by optical pumping with a laser diode. This method provides superior utilization of Cs atoms, and provides the potential advantages of: higher S/N, longer life, lower weight, and the possibility of trading off size for accuracy.  A miniature Cs standard of 1 x 10-11 accuracy, and <<1 liter volume, i.e., about 100x higher accuracy than a Rb standard, in a smaller volume (but not necessarily the same shape factor) seems possible.
Fluorescence Detector
·
Detection
laser
Pump
laser(s)
Oven
Essential Elements of an Optically Pumped
Cesium Beam Standard
62 P 3/2
62 S 1/2
F = 5
F = 4
F = 3
F = 4
F = 3
State selection
State detection
Tuned laser
diode pumps
Spontaneous
decays
453 MHz
852 nm
(~350 THz)
9.192631770 GHz
Atomic Energy Levels
Optically Pumped Cs Standard
   The optical pumping technique manipulates the populations in the hyperfine levels of the ground state by exciting transitions to higher principal quantum states with infrared, or higher frequency, light.  As shown above, the atoms in one hyperfine level are excited optically to a higher state from which they decay spontaneously to both ground state hyperfine levels.  The population of the hyperfine state involved in the stimulated transition is rapidly depleted; the population of the second hyperfine level is enhanced.  Microwaves applied at the 9.192…GHz frequency can be locked to the atomic transition frequency, as in a Cs beam standard.
   Optical pumping has both advantages and disadvantages compared to magnetic state selection.  On the positive side, it can be accomplished in a more compact device and it can enhance the number of atoms in the desired state rather than just rejecting the atoms in the undesired state.  On the negative side are increases in complexity, the difficulty of obtaining laser diodes at the proper frequency and with suitable stability (as of 1999), and some additional performance-degrading mechanisms.
   Optical pumping can eliminate the need for state-selection magnets, and result in a larger number of atoms contributing to the signal which results in a superior signal-to-noise ratio.  In addition, the spatial symmetry of the optical pumping reduces certain frequency shifts.


L. L. Lewis, “Miniature Optically Pumped Cesium Standards,” Proc. 45th Ann. Symp. on Frequency Control, pp. 521-533, 1991.

P. J. Chantry, B. R. McAvoy, J. M. Zomp, and I. Liberman, “Towards A Miniature Laser-pumped Cesium Cell Frequency Standard,” Proc. 1992 IEEE Int’l Frequency Control Symp., pp. 114-122, 1992.

P. J. Chantry, I. Liberman, et. al, “Miniature Laser Pumped Cesium Cell Atomic Clock Oscillator,” Proc. 1996 IEEE Int’l Frequency Control Symp., pp. 1002-1010, 1996.