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When a fast neutron hurtles into a crystal
lattice and collides with an atom, it is scattered like a billiard ball. A single such neutron can produce numerous
vacancies, interstitials, and broken interatomic bonds (see next page). The effect of this "displacement
damage" on oscillator frequency is dependent primarily upon the neutron
fluence (and not on the type of quartz).
The frequency of oscillation increases nearly linearly with neutron
fluence at rates of: 8 x 10-21
neutrons per square centimeter (n/cm2) at a fluence range of 1010
to 1012 n/cm2, 5 x 10-21/n/cm2 at
1012 to 1013 n/cm2, and 0.7 x 10-21/n/cm2
at 1017 to 1018 n/cm2.
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J. C. King and D. B.
Fraser, "Effects of Reactor Irradiation on Thickness Shear Crystal
Resonators," Proc. 16th Annual Symposium on Frequency Control, pp. 8-31,
1962, AD-285086.
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T. M. Flanagan &
T. F. Wrobel, “Radiation Effects in Swep-Synthetic Quartz,” IEEE Trans.
Nuclear Science, vol. NS-16, pp. 130-137, Dec. 1969
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W. Primak,
“Extrusion of Quartz on Ion Bombardment: Further Evidence for
Radiation-Induced Stress Relaxation of the Silica Network,” Phys. Rev. B,
vol. 14, pp. 4679-4686, 1976.
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