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The above diagrams show qualitative models
of the possible positions of H+ and alkali ions in the channels of
the quartz lattice, and the corresponding trends in the potential energy
curves. The arrows show the main
channels in the quartz lattice - along the z-axis. It takes much less force to move ions along
this channel than along other directions.
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The H+ ion is strongly bound to
the O ions; A) and B) show two possible models of H+ in quartz
(due to Kats). As the OH bond is very
strong, it is unlikely for a H+ to move along the channel at
normal temperatures. C) to E) show the
positions of alkali ions in the channels and the corresponding
potentials. There is a potential well
of ~1 eV depth around the Al3+ ion. Superimposed on that are a series of low
potential barriers along the channel that are shown above. In the Li+ case, only one kind
of transition is likely. In the Na+
and K+ cases, two different kinds of transitions are likely.
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When the Q of a resonator is measured as a
function of temperature, defects such as the Al-alkali centers cause acoustic
losses as the thermally activated alkalis couple to the oscillating stress
field; e.g., the Al-Na+ center causes an acoustic loss peak at 50
K in 5 MHz 5th overtone AT-cut resonators. Above room temperature, the
interstitial alkalis are thermally liberated and diffuse along the z-axis
which results in Q losses that increase exponentially with temperature. Such
Q losses, and the Al-Na+ loss peak are not present in swept
crystals (see “Sweeping” later in this chapter).
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Ionizing radiation creates electron-hole
pairs that make a transient electrical conductivity increase. It also liberates ions and allows the ions
to move from one potential well to another, thereby changing the elastic
constants. A pulse of radiation
thereby causes both a transient and steady-state change in the resonator’s
frequency (see radiation effects discussion in chapter 4).
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J. M. Stevels and J. Volger, “Further
Experimental Investigations on the Dielectric Losses of Quartz Crystals in
Relation to Their Imperfections,” Philips Res. Reports. 17, pp. 283-314,
1962.
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A. Kats, “Hydrogen in Alpha-quartz, Philips
Res. Reports. 17, pp. 133-195, 201-279, 1962.
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L. E. Halliburton, J. J. Martin & D. R.
Koehler, “Properties of Piezoelectric Materials,” in E. A. Gerber and A.
Ballato, Precision Frequency Control, Vol. 1, pp. 1-45, Academic
Press, 1985.
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